Poly( -benzyl-L-glutamate)(PBLG) Ionomers Masanori Hara ...

Poly( -benzyl-L-glutamate)(PBLG) Ionomers Masanori Hara ...

Poly(-benzyl-L-glutamate)(PBLG)benzyl-benzyl-L-glutamate)(PBLG)L-benzyl-L-glutamate)(PBLG)glutamate)(PBLG) Ionomers
Masanori Hara, Department of Chemical and Biochemical
Engineering,
Rutgers, The State University of New Jersey, Piscataway, NJ 08854
We try to develop a series of new polypeptide ionomers that use a-amino acids as building
blocks. As a first step, we are studying a simple model system, i.e., model random ionomers,
poly(-benzyl-L-glutamate)(PBLG) ionomers. We stress the effect of benzyl-benzyl-L-glutamate)(PBLG) ionomers. We stress the effect of L-benzyl-L-glutamate)(PBLG) ionomers. We stress the effect of glutamate)(PBLG) ionomers. We stress the effect of ionic groups
(interactions) on the structures and properties of PBLG. With an increase in the ionic content,
chain conformation changes from a rod (helical structure), to a broken rod , and to a random
coil due to the existence of ionic groups (and ionic interactions). PBLG ionomers with a small
amount of ionic groups develop thermotropic liquid crystalline behavior due to partial
disruption of -benzyl-L-glutamate)(PBLG) ionomers. We stress the effect of helical structure in contrast to PBLG and acid form PBLG, which maintain
helical structures and, as a result, are difficult to process.

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